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Cu2Mn1xCoxSnS4: Novel kesterite type solid solutions
| dc.contributor.author | López-Vergara, Fernanda | |
| dc.contributor.author | Galdámez, Antonio | |
| dc.contributor.author | Manríquez, Victor | |
| dc.contributor.author | Barahona-Huenchumil, Patricia | |
| dc.contributor.author | Peña, Octavio | |
| dc.date.accessioned | 2017-11-14T17:48:22Z | |
| dc.date.available | 2017-11-14T17:48:22Z | |
| dc.date.issued | 2013 | |
| dc.identifier.uri | http://repositorio.ucm.cl/handle/ucm/1238 | |
| dc.description.abstract | A new family of Cu2Mn1xCoxSnS4 chalcogenides has been synthesized by conventional solid-state reactions at 850 1C. The reactions products were characterized by powder X-ray diffraction (XRD), energy-dispersive X-ray analysis (SEM-EDS), Raman spectroscopy and magnetic susceptibility. The crystal structures of two members of the solid solution series Cu2Mn0.4Co0.6SnS4 and Cu2Mn0.2Co0.8SnS4 have been determined by single-crystal X-ray diffraction. Both phases crystallize in the tetragonal kesterite-type structure (space group ¨ I4). The distortions of the tetrahedral volume of Cu2Mn0.4 Co0.6SnS4 and Cu2Mn0.2Co0.8SnS4 were calculated and compared with the corresponding differences in the Cu2MnSnS4 (stannite-type) end-member. The compounds show nearly the same Raman spectral features. Temperature-dependent magnetization measurements (ZFC/FC) and high-temperature susceptibility indicate that these solid solutions are antiferromagnetic. | es_CL |
| dc.language.iso | en | es_CL |
| dc.rights | Atribución-NoComercial-SinDerivadas 3.0 Chile | * |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/cl/ | * |
| dc.source | Journal of Solid State Chemistry, 198, 386-391 | es_CL |
| dc.subject | Chalcogenides | es_CL |
| dc.subject | Synthesis | es_CL |
| dc.subject | Crystal structure | es_CL |
| dc.subject | Kesterite | es_CL |
| dc.title | Cu2Mn1xCoxSnS4: Novel kesterite type solid solutions | es_CL |
| dc.type | Article | es_CL |
| dc.ucm.facultad | Facultad de Ciencias Básicas | es_CL |
| dc.ucm.indexacion | Scopus | es_CL |
| dc.ucm.indexacion | Isi | es_CL |
| dc.ucm.uri | sibib2.ucm.cl:2048/login?url=https://www.sciencedirect.com/science/article/pii/S0022459612006731?via%3Dihub | es_CL |
| dc.ucm.doi | doi.org/10.1016/j.jssc.2012.10.026 | es_CL |
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Excepto si se señala otra cosa, la licencia de la publicación se describe como Atribución-NoComercial-SinDerivadas 3.0 Chile