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Development of eco-friendly polyurethane foams based on Lesquerella fendleri (A. Grey) oil-based polyol

dc.contributor.authorContreras-González, Jorge
dc.contributor.authorValdés-Lizama, Oscar
dc.contributor.authorMirabal-Gallardo, Yaneris
dc.contributor.authorDe la Torre, Alexander F.
dc.contributor.authorNavarrete, José
dc.contributor.authorLisperguer, Justo
dc.contributor.authorDurán-Lara, Esteban F.
dc.contributor.authorSantos, Leonardo S.
dc.contributor.authorNachtigall, Fabiane M.
dc.contributor.authorCabrera-Barjas, Gustavo
dc.contributor.authorabril, diana
dc.date.accessioned2020-08-20T18:58:42Z
dc.date.available2020-08-20T18:58:42Z
dc.date.issued2020
dc.identifier.urihttp://repositorio.ucm.cl/handle/ucm/3021
dc.description.abstractIn this study, we investigated the potential of polyurethane foams (LPUF) prepared from Lesquerella fendleri (A. Grey) oil-derived polyol to use as an ecological and cheap substitute for the petroleum-based polyurethane foams. The polyol was synthesized by a one-single step reaction using a mixture of hydrogen peroxide and acetic acid. The L. fendleri oil and the synthetized polyol were characterized by their physical–chemical properties as well as chromatographic analysis, iodine value, yield, saponification number, kinematic viscosity, density, theorical molecular weight, hydroxyl number, 1H and 13C NMR spectroscopy, attenuated total reflectance Fourier-transform infrared (ATR-FTIR) and Thermogravimetric analysis (TGA). The obtained L. fendleri oil-based polyol reacted with aromatic diphenylmethane diisocyanate in the presence of water, N,N,N′,N′′,N′′-Pentamethyldiethylenetriamine, stannous 2-ethylhexanoate and silicone, which were used as a blowing agent, catalysts and surfactant, respectively, to produce LPUF. The effects of the amount of diphenylmethane diisocyanate on apparent density values, compression test, and the average pore size of LPUFs property were studied. The results revealed that all these properties are correlated with the MDI amount. The ATR-FTIR, TGA, SEM and selective degradation test were performed for the LPUFs, which revealed that the foam formations were successful. We obtained a macroporous structure with a combination of both open and closed cells that is more thermoresistant than the precursors with degradation products derived from hydroxylated lesquerolic (major) and linolenic (minor) acids.es_CL
dc.language.isoenes_CL
dc.rightsAtribución-NoComercial-SinDerivadas 3.0 Chile*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/cl/*
dc.sourceEuropean Polymer Journal, 128, 109606es_CL
dc.subjectLesquerella fendleries_CL
dc.subjectVegetable oiles_CL
dc.subjectPolyoles_CL
dc.subjectPolyurethane foamses_CL
dc.subjectRenewable resourcees_CL
dc.titleDevelopment of eco-friendly polyurethane foams based on Lesquerella fendleri (A. Grey) oil-based polyoles_CL
dc.typeArticlees_CL
dc.ucm.indexacionScopuses_CL
dc.ucm.indexacionIsies_CL
dc.ucm.urisibib2.ucm.cl:2048/login?url=https://www.sciencedirect.com/science/article/abs/pii/S0014305720301701es_CL
dc.ucm.doidoi.org/10.1016/j.eurpolymj.2020.109606es_CL


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