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dc.contributor.authorJayaramudu, Tippabattini
dc.contributor.authorPyarasani, Radha D.
dc.contributor.authorAkbari-Fakhrabadi, A.
dc.contributor.authorabril, diana
dc.contributor.authorAmalraj, John
dc.date.accessioned2021-12-28T14:03:22Z
dc.date.available2021-12-28T14:03:22Z
dc.date.issued2021
dc.identifier.urihttp://repositorio.ucm.cl/handle/ucm/3672
dc.description.abstractIn this research work, a novel gum acacia capped polyaniline-based nanocomposite hydrogel (GPA NCHs) was developed and evaluated for the adsorptive removal of cationic methylene blue dye (MB) from aqueous solutions. Firstly, Gum acacia (GA) capped Polyaniline (PANI) dispersion was synthesized by using dispersion polymerization. Then, a water-swellable hydrogel network consisting of GA-PANI and acrylamide (AM) was obtained by using N,N′ -methylene-bisacrylamide (MBA) as a cross-linker, and ammonium persulphate/N,N,N′,N′-tetramethylethylenediamine (APS/TMEDA) as an initiating system. The developed materials were characterized by UV–visible, FTIR, XRD, SEM–EDX and TEM techniques. The microscopy studies revealed that GA-PANI nanoparticles have a granular morphological surface with an average size of ~ 40–100 nm. Removal of MB dye from aqueous system was performed by adsorption studies in batch equilibrium mode with different dosage of GA-PANI, MB concentration, pH and temperatures. The adsorption data revealed that the absorption capacity of GPA NCHs highly depends on the dosage of GA-PANI, pH and concentration of the MB dye. The maximum percentage of MB removal onto GPA 1.0 NCHs was found to be 89% at pH 10 with a dye concentration of 10 mg L−1. The equilibrium adsorption data were also analyzed by different models to understand the adsorption process. The results revealed that the adsorption process followed the pseudo-second-order kinetics and it fit well in Langmuir and Freundlich adsorption isotherms with a maximum adsorption capacity of 35.41 mg g−1. These studies demonstrate that the GPA NCHs could be a promising adsorbent material for the removal of MB dye from contaminated aqueous systems.es_CL
dc.language.isoenes_CL
dc.rightsAtribución-NoComercial-SinDerivadas 3.0 Chile*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/cl/*
dc.sourceJournal of Polymers and the Environment, 29, 2447-2462es_CL
dc.subjectNanocomposite hydrogelses_CL
dc.subjectPolyanilinees_CL
dc.subjectMethylene bluees_CL
dc.subjectAdsorptiones_CL
dc.titleSynthesis of gum acacia capped polyaniline-based nanocomposite hydrogel for the removal of methylene blue dyees_CL
dc.typeArticlees_CL
dc.ucm.indexacionScopuses_CL
dc.ucm.indexacionIsies_CL
dc.ucm.urilink.springer.com/article/10.1007/s10924-021-02066-wes_CL
dc.ucm.doidoi.org/10.1007/s10924-021-02066-wes_CL


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